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2,7-Pyrenedicarboxylic acid

  • Name 2,7-Pyrenedicarboxylic acid
  • CAS 214622-81-8
  • Purity 99%
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Product Details

99% Purity Commercial production 2,7-Pyrenedicarboxylic acid 214622-81-8 with Cheapest Price

  • Molecular Formula: C18H10O4
  • Molecular Weight: 290.275
  • PSA: 74.60000 
  • LogP: 3.98040 

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214622-81-8 Process route

carbon dioxide
124-38-9,18923-20-1

carbon dioxide

2,7-dibromo-4,5,9,10-tetrahydropyrene
102587-98-4

2,7-dibromo-4,5,9,10-tetrahydropyrene

pyrene-2,7-dicarboxylic acid
214622-81-8

pyrene-2,7-dicarboxylic acid

Conditions
Conditions Yield
With n-butyllithium; In diethyl ether; at -78 - 20 ℃; Acidic conditions;
96%
2,7-dibromo-4,5,9,10-tetrahydropyrene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;
carbon dioxide; In tetrahydrofuran; hexane; at 20 ℃; Inert atmosphere;
91%
With n-butyllithium; In tetrahydrofuran; at -78 ℃;
pyrene
129-00-0

pyrene

pyrene-2,7-dicarboxylic acid
214622-81-8

pyrene-2,7-dicarboxylic acid

Conditions
Conditions Yield
Multi-step reaction with 3 steps
1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / tetrahydrofuran / 16 h / 80 °C / Inert atmosphere
2: copper(ll) bromide / tetrahydrofuran; methanol; water / 16 h / 90 °C
3: n-butyllithium / diethyl ether / -78 - 20 °C / Acidic conditions
With n-butyllithium; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; copper(ll) bromide; In tetrahydrofuran; methanol; diethyl ether; water;
Multi-step reaction with 3 steps
1.1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / tetrahydrofuran / 16 h / 80 °C / Schlenk technique; Inert atmosphere; Sealed tube
2.1: copper(ll) bromide / tetrahydrofuran; methanol; water / 90 °C
3.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere
3.2: 20 °C / Inert atmosphere
With n-butyllithium; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; copper(ll) bromide; In tetrahydrofuran; methanol; hexane; water;

214622-81-8 Upstream products

  • 129-00-0
    129-00-0

    pyrene

  • 124-38-9
    124-38-9

    carbon dioxide

  • 102587-98-4
    102587-98-4

    2,7-dibromo-4,5,9,10-tetrahydropyrene

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