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2,7-Pyrenedicarboxylic acid
- Name 2,7-Pyrenedicarboxylic acid
- CAS 214622-81-8
- Purity 99%
Product Details
99% Purity Commercial production 2,7-Pyrenedicarboxylic acid 214622-81-8 with Cheapest Price
- Molecular Formula: C18H10O4
- Molecular Weight: 290.275
- PSA: 74.60000
- LogP: 3.98040
214622-81-8 Relevant articles
Ligand Rigidification for Enhancing the Stability of Metal-Organic Frameworks
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Metal-organic frameworks (MOFs) have bee...
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Synthesis of 2-and 2,7-functionalized pyrene derivatives: An application of selective C-H borylation
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An efficient synthetic route to 2-and 2,...
214622-81-8 Process route
-
-
124-38-9,18923-20-1
carbon dioxide
-
-
102587-98-4
2,7-dibromo-4,5,9,10-tetrahydropyrene
-
-
214622-81-8
pyrene-2,7-dicarboxylic acid
| Conditions | Yield |
|---|---|
|
With
n-butyllithium;
In
diethyl ether;
at -78 - 20 ℃;
Acidic conditions;
|
96%
|
|
2,7-dibromo-4,5,9,10-tetrahydropyrene;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.5h;
Inert atmosphere;
carbon dioxide;
In
tetrahydrofuran; hexane;
at 20 ℃;
Inert atmosphere;
|
91%
|
|
With
n-butyllithium;
In
tetrahydrofuran;
at -78 ℃;
|
-
-
129-00-0
pyrene
-
-
214622-81-8
pyrene-2,7-dicarboxylic acid
| Conditions | Yield |
|---|---|
|
Multi-step reaction
with
3
steps
1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / tetrahydrofuran / 16 h / 80 °C / Inert atmosphere
2: copper(ll) bromide / tetrahydrofuran; methanol; water / 16 h / 90 °C
3: n-butyllithium / diethyl ether / -78 - 20 °C / Acidic conditions
With
n-butyllithium; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; copper(ll) bromide;
In
tetrahydrofuran; methanol; diethyl ether; water;
|
|
|
Multi-step reaction
with
3
steps
1.1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / tetrahydrofuran / 16 h / 80 °C / Schlenk technique; Inert atmosphere; Sealed tube
2.1: copper(ll) bromide / tetrahydrofuran; methanol; water / 90 °C
3.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere
3.2: 20 °C / Inert atmosphere
With
n-butyllithium; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; copper(ll) bromide;
In
tetrahydrofuran; methanol; hexane; water;
|
214622-81-8 Upstream products
-
129-00-0
pyrene
-
124-38-9
carbon dioxide
-
102587-98-4
2,7-dibromo-4,5,9,10-tetrahydropyrene
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